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The Real Story of Bad Diesel Fuel
Posted on Sunday, February 11 @ 12:00:43 CET by Harry

Truckstop Canada News: Frequent diesel fuel filter changes and the expensive and time consuming task of cleaning diesel fuel tanks have become acceptable periodic maintenance instead of a warning signal for diesel engine failure. Diesel fuel filter elements should last a thousand hours or more, and injectors some 15,000 hours. However, since diesel fuel is inherently unstable, solids begin to form and the accumulating tank sludge will eventually clog your diesel fuel filters, ruin your injectors and cause diesel engines to smoke.


Symptoms...

Clogged and slimy filters

Dark, hazy fuel

Sludge build up in tanks

Loss of power and RPM

Excess smoke

Corroded, pitted injectors

Foul odor



The solids that form as the result of the inherent instability of the diesel fuel and the debris formed in the natural process of fuel degradation will accumulate in the bottom of your fuel tank. The sludge will form a coating or bio-film on the walls and baffles of the fuel tank, plug your fuel filters, adversely impact combustion efficiency, produce dark smoke from the exhaust, and impact performance. Eventually fouled diesel fuel will clog fuel lines and ruin your equipment.......................>>



Filter plugging can have several causes and often critical consequences. For example, low temperatures can cause wax crystallization, which can lead to fuel filter plugging. An example would be using untreated summer diesel fuel in cold weather. Wax or paraffin is part of the diesel fuel.


Contaminant build up resulting from excessive microbial growth and bio-degradation of diesel fuel can cause fuel filter plugging. Micro-organisms, bacteria and enzyme activity, fungus, yeast and mold cause diesel fuel degradation and the formation of waste products. The process is similar to milk turning into cottage cheese, a different form of milk. Of all the microbial debris and waste products in the diesel fuel tank only about .01% is "bugs". Even though microbes may cause and accelerate the process of fuel degradation, it should be clear that the waste products clogging your filter are not the microbes but fuel components which have formed solids.


Frequently, the application of a biocide aggravates the situation and turns bio-film into solids, creating a real fuel filter nightmare. Bio film develops throughout the entire diesel fuel system. It grows in the water-fuel interface and on the walls, baffles, and bottoms of fuel storage tanks. An unlucky end user may be filling up his fuel tank and getting this debris delivered as a part of his diesel fuel, for the same price as the diesel fuel.


Chemical incompatibility may cause dramatic filter plugging. This may happen when fuels with incompatible additive packages are mixed.


A diesel engine uses only some of the fuel it pulls from the tank. All of that fuel goes through the high-pressure fuel pump and to the injectors operating under enormous pressure and high temperatures. The surplus fuel the engine is not using goes back to the tank. This fuel is continuously re-circulated and exposed to extreme pressure and heat, which results in the agglomeration of asphaltenes, the high carbon content, heavy end fuel molecules. It leads to the formation of larger and larger clusters and solids, which are very difficult to completely combust. These solids may grow so large that they will not pass through the filter element. They become part of the polymer and sludge build up plugging the filter.


More than 90% of the debris on filter elements and the sludge in our tanks is organic material: fuel and oil breakdown residue. Adding biocide does not help! In most cases, this debris is acidic and not good for your engine. It causes corrosion in injectors, pumps and storage tanks.


In addition, the hot fuel coming back to the tank will raise the fuel temperature in the tank, cause condensation and contribute to microbial contamination, fuel break down, bio fouling and the build up of sludge and acid.


Large fuel droplets and high asphaltene concentrations require more time, more energy and higher temperatures to combust than is available in engines during the combustion cycle and before the exhaust valve opens. Any device in the fuel system exposing the fuel to stress (heat and pressure) such as pumps, heaters, or centrifuges will increase the formation of asphaltenes. If you have seen fuel that has turned dark, or almost black, in comparison to clear, bright fuel, then you have witnessed the results of this process. This degraded, dark fuel negatively impacts combustion.


The diesel fuel of today is not the same as what was available years ago. Up until about 15-20 years ago, refineries used only about 50% of a barrel of crude oil to make distillates such as gasoline, jet fuel and diesel fuel. The remainder of the barrel of crude oil went to "residual oil" such as lubricating oils and heavy oils. Today, as a result of different refining techniques and additive packages, the refinery uses 85% or more of the same barrel of crude, which clearly has consequences for fuel stability. In addition, new requirements of low sulfur fuels further impacts fuel performance.


Poor thermal fuel stability can plug filters. Fuel will form particulates (solids) when exposed to pumps and the hot surfaces and pressure of the fuel injection system. This will result in an increase in asphaltene agglomerations, polymerization and a dramatic loss of combustion efficiency.


Fuel systems, in general, are designed to return a significant proportion of the fuel not used for combustion back to the tank. This return fuel is very hot and will promote polymerization and fuel breakdown. Eventually, more and more solids from the tank will reach the filter and over time, plug the filter. These problems continuously occur in commercially operated engines, such as trucks, heavy equipment, shipping, and power generation, but will also appear in recreational boats, RV's and all types of fuel storage tanks.


Truck engines are used continuously and, in most cases, the tanks "appear to be clean". However, a 2-micron filter element does not last very long, in general 15,000 miles or less. It should be 30,000 miles or more. In the marine industry filter changes of 400 hours is in many instances standard operating procedure, while filters should easily last 1,000 hours or more.


Short filter life is quite remarkable realizing how "thin" diesel fuel actually is and knowing how clean the tanks on most trucks "appear" to be.


Short filter life is symptomatic of polymerization, increase in the size of the fuel droplet, agglomeration of asphaltenes and the formation of solids in fuel systems. The consequences are carbon build up in engines and exhaust systems, higher fuel consumption and excessive smoke.


The stuff that clogs your filters is actually fuel in some way, shape or form. In excess of 90% of this organic debris are fuel breakdown products. It is not sand, dust, stones, rust or in-organic matter that blocks your filter.


The inorganic material like sand, dust and other particles will not cause your filters to clog. In fact, a lot of sand in a fuel filter would act as extra filtration. The pores between the sand particles are much larger than the pores in a standard fuel filter element. Sand filters are commonly used to filter water. A hair is approximately 40 micron and fuel filter elements range all the way from 30 micron for a pre-filter to 2 micron in a fine filter.


Fuel stability is a serious concern for the diesel fuel user.


The chemistry of diesel fuel instability involves the chemical conversion of precursors to species of higher molecular weight with limited solubility. The conversion process often involves oxidation of the precursors. Fuel solvency plays a role since the development of insolubles is always a function of both the presence of higher molecular weight species and the fuel capacity to dissolve them.


Fuel is an unstable, organic liquid that goes "bad". Your vendor will always sell you the highest fuel quality possible. However, due to a variety of circumstances fuel may have "aged", oxidized and/or may contain water. It may have been contaminated before it was delivered to you or to your vendor.


Fuel has to travel from the refinery to the end user destination. It is pumped through pipelines, barged, trucked and stored in tank farms. Changes in temperature throughout any given day and exposure to the atmosphere will cause condensation and water in storage systems. As a result, your fuel quality diminishes.


When your fuel is finally used, it is exposed to the heat and pressure of engine injection systems, centrifuges, pumps, and heaters causing an increase in asphaltene agglomerations, which negatively impacts combustion efficiency and emissions.


Fuel is made to certain ASTM specifications and diesel engines are designed and built to operate on fuels that consistently meet these specifications. When it does not meet these specifications, we could refer to it as "bad fuel". However, we tend to refer to fuel as "bad fuel" when we see symptoms such as: •dark hazy fuel, •filter plugging, •sludge build up in tanks, •poor engine performance, •excessive smoke & •emissions, •etc. We refer to fuel as "good fuel", when it is clear and bright. Or rather in that case, no reference is made at all to our fuel. We simply use it and take fuel quality and peak engine performance for granted.


Dark fuel is symptomatic of poor quality and even though, in most cases, it can be used, fuel in this condition will provide poor combustion and filtration problems.


"Dark fuel" is in general indicative of oxidation and that the process of fuel degradation is in a far advanced stage. Hazy fuel is indicative of water emulsified in the fuel. In general, dark hazy fuel will not damage your engine. Howver, it does indicates poor fuel quality which will definitely not provide you with peak engine performance.


As long as fuel meets the (ASTM) specifications, it will perform in your engine. Using fuel that is less than optimal quality negatively impacts engine efficiency and accelerates the process that makes new engines old.


Diesel fuel can range from colorless to amber or light brown in color depending on the crude oil and the refinery process used to produce it. In addition, dyes may be added to change the fuel color for tax identification purposes.


In time, stored fuel will darken due to oxidation, repolymerization and agglomeration of certain components. The darkening is accompanied by the formation of sediment that plugs filters and causes poor combustion. Fuel & Oil vendors know what time can do to fuel quality and suggest that if diesel fuel is stored for emergency use, it should be replaced with fresh fuel within a year, unless special precautions or remedial actions are taken.


The University of Idaho conducted tests on the life expectancy of fuels to determine the timeline on degradation of stored #2 diesel fuel. The results indicated 26% degradation after 28 days of storage. Disposing of fuel and purchasing new fuel is a very expensive proposition. Many larger companies, government institutions, hospitals, etc. have the dumping of fuel and the purchasing of new fuel as standard and accepted practice. Some systems are designed to dispose of the degraded fuel into facility boilers periodically. But this, too, if adequately analyzed, will show that this means of dealing with the problem is deemed acceptable only because it is designed into the system instead of addressing the root-cause of the problem.


The implementation of ALGAE-X Technology eliminates these costly, wasteful, and environmentally unfriendly dumping practices. ALGAE-X will preserve fuel integrity almost indefinitely and can help you put in place good housekeeping measures along with a quality fuel-monitoring program.

 
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